• Dr. Hideki Shirakawa


    Biography

    1961 Graduated from Department of Chemical Engineering, Faculty of Engineering, Tokyo Institute of Technology
    1961-1966 Graduate School of Engineering (Major in Engineering), Tokyo Institute of Technology
    1966 Receives PhD in Engineering, Tokyo Institute of Technology: Research on block chains of copolymer
    1966 Assistant at the Chemical Resources Laboratory, Tokyo Institute of Technology
    1976 Doctorate researcher at University of Pennsylvania
    1979 Associate Professor of Institute of Materials Science, University of Tsukuba
    1982 Professor of Institute of Materials Science, University of Tsukuba
    2000 Retired from the University of Tsukuba, and became Professor Emeritus

    Awards

    1983 The Award of the Society of Polymer Science, Japan (FY 1982): Research on polyacetylene
    2000 SPSJ Award for Outstanding Achievement in Polymer Science and Technology (FY 1982)
    2000 Nobel Prize in Chemistry
    2000 Order of Culture and selected as Person of Cultural Merit
    2000 Professor Emeritus of the University of Tsukuba
    2001 Special Award of the Chemical Society of Japan

    Research Works

    Dr. Shirakawa pioneered a new field of "conductive polymers" by challenging the commonly held view that polymers do not conduct electricity. His main works can be classified into the following four.

    1) Synthesis of polyacetylene thin films

    Although polyacetylene was expected to have specific optical and electronic properties, its insolubility and infusibility obstructed the progress of research. Dr. Shirakawa found that polyacetylene thin films can be synthesized by polymerizing acetylene at the interface of concentrated Ziegler-Natta catalyst solutions. With the thin films, he clarified the molecular and solidified structures of polyacetylene.

    2) Creation of metallic conductivity due to chemical doping

    Dr. Shirakawa found that, when a trace of a halogen such as bromine or iodine is added to thin film polyacetylene, its electric conductivity increases and it exhibits metallic conductivity. By various spectroscopic measurements and evaluations of the physical properties of polyacetylene, he clarified that partial electron transfer between dopants and p-electrons of polyacetylene can generate metallic conductivity.

    3) Development of acetylene polymerization using liquid crystals as solvents

    Using liquid crystals as solvents, Dr. Shirakawa developed a method for the production of highly conductive polyacetylene thin films consisting of uni-axially oriented fibrils of polymer chains, in parallel with the polymerization of acetylene. Furthermore, by the polymerization of acetylene in chiral nematic liquid crystals, he succeeded in the synthesis of thin films of helical polyacetylene whose chirality is controllable.

    4) Creation of conjugated liquid crystalline polymers

    Dr. Shirakawa created self-oriented, conjugated liquid crystalline polymers by introducing liquid crystalline groups into the side chains of p-conjugated polymers such as polyacetylene. Furthermore, by macroscopically orienting the polymers with electric or magnetic fields, he succeeded in them having electric anisotropy and optical dichroizm.
    For these pioneering works, Dr. Shirakawa received the Award of the Society of Polymer Science, Japan, the SPSJ Award for Outstanding Achievement in Polymer Science and Technology, and the Nobel Prize in Chemistry. Currently, the application of conductive polymers has spread widely to various new fields, such as light-emitting polymer diodes, new color screens, and polymer batteries. In the 21st century, it is expected that plastic electronics based on conductive polymers and molecular electronics built just on molecules may develop from this.

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